期刊
CATALYSTS
卷 5, 期 3, 页码 1603-1621出版社
MDPI AG
DOI: 10.3390/catal5031603
关键词
titanium dioxide; MCM-48; cubic mesoporous materials; cyclohexene; epoxidation
资金
- NSF-EPSCoR [EPS-0554609, NSF-CHE-0840507, NSF-CHE-0722632]
Titania containing cubic MCM-48 mesoporous materials were synthesized successfully at room temperature by a modified Stober method. The integrity of the cubic mesoporous phase was retained even at relatively high loadings of titania. The TiO2-MCM-48 materials were extensively characterized by a variety of physico-chemical techniques. The physico-chemical characterization indicate that Ti4+ ions can be substituted in framework tetrahedral positions. The relative amount of Ti4+ ions in tetrahedral position was dependent on the order of addition of the precursor. Even at relatively high loadings of titania, no distinct bulk phase of titania could be observed indicating that the titania nanoclusters are well dispersed on the high surface area mesoporous material and probably exist as amorphous nanoclusters. The TiO2-MCM-48 materials were found to exhibit 100% selectivity in the cyclohexene oxidation at room temperature in the presence of tert-butylhydroperoxide (t-BHP) as the oxidant. The results suggest that room temperature synthesis is an attractive option for the preparation of TiO2-MCM-48 materials with interesting catalytic properties.
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