期刊
SCIENTIFIC REPORTS
卷 6, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/srep21177
关键词
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资金
- MOST [2014CB239702]
- National Science Foundation of China [51302083, 51172071, 51272077]
- Fundamental Research Funds for the Central Universities and Shanghai Rising-Star Program
Li-ion intercalation materials with extremely high rate capability will blur the distinction between batteries and supercapacitors. We construct a series of nanoarchitectured intercalation materials including orthorhombic (o-) Nb2O5 hollow microspheres, o-Nb2O5@carbon core-shell microspheres and tetragonal (t-) NbO2@carbon core-shell microspheres, through a one-pot hydrothermal method with different post-treatments. These nanoarchitectured materials consist of small nanocrystals with highly exposed active surface, and all of them demonstrate good Li+ intercalation pseudocapacitive properties. In particular, o-Nb2O5 hollow microspheres can deliver the specific capacitance of 488.3 F g(-1), and good rate performance of 126.7 F g(-1) at 50 A g(-1). The o-Nb2O5@carbon core-shell microspheres show enhanced specific capacitance of 502.2 F g(-1) and much improved rate performance (213.4 F g(-1) at 50 A g(-1)). Furthermore, we demonstrate for the first time, t-NbO2 exhibits much higher rate capability than o-Nb2O5. For discharging time as fast as 5.9 s (50 A g(-1)), it still exhibits a very high specific capacitance of 245.8 F g-1, which is 65.2% retention of the initial capacitance (377.0 F g(-1) at 1 A g(-1)). The unprecedented rate capability is an intrinsic feature of t-NbO2, which may be due to the conductive lithiated compounds.
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