期刊
SCIENTIFIC REPORTS
卷 4, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/srep04098
关键词
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资金
- National Natural Science Foundation of China [NSFC-21173007, 11274023]
- National Grand Fundamental Research 973 Program of China [2012CB921404]
Two-dimensional organometallic sheets containing regularly and separately distributed transition atoms (TMs) have received tremendous attentions due to their flexibility in synthesis, well-defined geometry and the promising applications in hydrogen storage, electronic circuits, quantum Hall effect, and spintronics. Here for the first time we present a study on the superior catalytic CO oxidation capacity of a Cr-phthalocyanine porous sheet proceeding first via Langmuir-Hinshelwood (LH) mechanism and then via Eley-Rideal (ER) mechanism. Compared to the noble metal based catalysts or graphene supported catalysts, our studied system has following unique features: without poisoning effect and clustering problem, having comparable reaction energy barrier for low-temperature oxidation, and low cost for large-scale catalytic CO oxidation in industry.
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