期刊
SCIENTIFIC REPORTS
卷 3, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/srep03234
关键词
-
资金
- Beijing Municipal Natural Science Foundation [2110001]
- National Natural Science Foundation of China [11179001]
- National High Technology Research and Development Program (863) [2012AA052201]
Insufficient durability and catalytic activity of oxygen reduction reaction (ORR) electrocatalyst are key issues that have to be solved for the practical application of low temperature fuel cell. This paper introduces a new catalyst design strategy using N-anchor to promote the corrosion resistance of electrocatalyst. The as-synthesized N-Pt3Fe1/C shows a high electrocatalytic activity and a superior durability towards ORR. The kinetic current density of N-Pt3Fe1/C as normalized by ECSA is still as high as 0.145 mA cm(-2) and only 7% loss after 20000 potential cycles from 0.6 to 1.2 V (vs. NHE) in O-2-bubbling perchloric acid solution, whereas Pt3Fe1/C shows 49% loss under the same tests. The N-anchor approach offers novel opportunities for the development of ORR catalyst with excellent electrochemical properties.
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