4.7 Article

Hierarchical silicon nanowires-carbon textiles matrix as a binder-free anode for high-performance advanced lithium-ion batteries

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SCIENTIFIC REPORTS
卷 3, 期 -, 页码 -

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NATURE PUBLISHING GROUP
DOI: 10.1038/srep01622

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资金

  1. National Natural Science Foundation [51002059, 21001046, 91123008]
  2. 973 Program of China [2011CB933300]
  3. Program for New Century Excellent Talents of the University in China [NCET-11-0179]
  4. Natural Science Foundation of Hubei Province [2011CDB035]

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Toward the increasing demands of portable energy storage and electric vehicle applications, the widely used graphite anodes with significant drawbacks become more and more unsuitable. Herein, we report a novel scaffold of hierarchical silicon nanowires-carbon textiles anodes fabricated via a facile method. Further, complete lithium-ion batteries based on Si and commercial LiCoO2 materials were assembled to investigate their corresponding across-the-aboard performances, demonstrating their enhanced specific capacity (2950 mAh g(-1) at 0.2 C), good repeatability/ rate capability (even >900 mAh g(-1) at high rate of 5 C), long cycling life, and excellent stability in various external conditions (curvature, temperature, and humidity). Above results light the way to principally replacing graphite anodes with silicon-based electrodes which was confirmed to have better comprehensive performances.

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