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Magnetic molecular materials with paramagnetic lanthanide ions

期刊

SCIENCE IN CHINA SERIES B-CHEMISTRY
卷 52, 期 11, 页码 1739-1758

出版社

SCIENCE PRESS
DOI: 10.1007/s11426-009-0275-9

关键词

lanthanide; coordination compound; magnetic coupling; magnetic ordering; magnetic relaxation; single-molecule magnet; single-chain magnet; single-ion magnet

资金

  1. National Natural Science Foundation of China [20821091, 20503001]
  2. National Basic Research Program of China [2006CB601102, 2009CB929403]

向作者/读者索取更多资源

The diverse magnetic properties of lanthanide-based magnetic molecular materials are introduced in the following organization. First, the general aspects of magnetic molecular materials and electronic states of lanthanide ions are introduced. Then the structures and magnetic properties are described and analyzed for molecules with one lanthanide ion, 4f-4f, 4f-3d and 4f-p magnetic coupling interactions. In each section, magnetic coupling, magnetic ordering and magnetic relaxation phenomenon are briefly reviewed using some examples. Finally, some possibilities of developing magnetic molecular materials containing lanthanide ions are discussed in the outlook part.

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