期刊
RSC ADVANCES
卷 8, 期 55, 页码 31666-31672出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra06708b
关键词
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资金
- National Natural Science Foundation of China [51502190]
- Program for the Outstanding Innovative Teams of Higher Learning Institutions of Shanxi
- Open Fund of the State Key Laboratory of Luminescent Materials and Devices (South China University of Technology) [2017-skllmd-01]
A series of Mn4+-activated CaLaMgSbO6 far-red-emitting phosphors were synthesized by a solid-state reaction route and the microstructure and optical characterizations were investigated in detail. Upon excitation at 370 and 469 nm, the samples showed intense far-red emission at about 708 nm originating from the E-2(g) (4)A(2g) transition and the optimal Mn4+ concentration was 0.7 mol%. The as-prepared phosphors also exhibited excellent internal quantum efficiency (88%) and high thermal stability. The emission intensity at room temperature dropped to 54% when the temperature rose to 423 K and the activation energy was 0.34 eV. The outstanding optical properties and the fact that the emission band of the obtained phosphors had a broad overlap with the absorption band of phytochrome P-FR demonstrated that the CaLaMgSbO6:Mn4+ phosphors may be promising potential spectral converters for applying to indoor plant cultivation light-emitting diodes.
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