期刊
RSC ADVANCES
卷 4, 期 79, 页码 42044-42053出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra04740k
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资金
- Special Research Fund of Hasselt University
- Research Foundation Flanders (FWO) [G.0555.10N]
- EU FP7 Collaborative Project MOLESOL [256617]
- Swedish Research Council Linnaeus grant
- Grant Agency of the Czech Republic [13-37383S]
Donor-acceptor type light-harvesting molecular wires are covalently attached to a boron-doped diamond surface via a combination of diazonium electrografting and Suzuki cross-coupling. For the Suzuki reaction, various catalytic systems are compared with respect to their imposed surface coverage. Combining 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl (SPhos) and Pd(0), the diamond coverage improves considerably (by 98%) as compared to the standard tetrakis(triphenylphosphine)palladium(0) (Pd(PPh3)(4)) catalyst. As the energy levels between the molecular chromophores and the diamond film align well, the sophisticated functionalized diamond surfaces present a first step towards the development of fully carbon-based devices for light to electricity conversion.
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