期刊
RSC ADVANCES
卷 4, 期 46, 页码 24170-24175出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra02779e
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资金
- National Natural Science Foundation of China [NSFC51032002, 11374162, 11274173]
- key Project of the National High Technology Research and Development Program (863 Program) of China [2011AA050526]
- Science and Technology Support Plan of Jiangsu Province [BE2011191]
- Natural Science Youth Foundation of Jiangsu Province [BK20130865]
- Scientific Research Foundation of Nanjing University of Posts and Telecommunications [NY213022, NY213113]
The hexagonal Na0.82Ca0.08Er0.16Y0.853F4 phosphor was prepared by the high temperature solid-state reaction. Novel six-photon ultraviolet up-conversion emissions in the range of 260-320 nm are observed under 1.54 mu m excitation. Using the ratio of 523 nm and 542 nm fluorescence emissions, low-temperature optical temperature sensing in the resulting phosphor is studied. The temperature sensitivity of the resulting phosphor in the region of 5-300 K is obtained by measuring the temperature dependent fluorescence intensity ratio of the 523 nm and 542 nm emissions originated from two thermally coupled H-2(11/2) and S-4(3/2) emitting levels. The temperature sensitivity with a maximum sensitivity of 0.0022 K-1 at 338 K is obtained experimentally. The results reveal that the resulting phosphor may be a promising material for the sensing system at low temperature.
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