4.6 Article

Magnetically recoverable and reusable CuFe2O4 nanoparticle-catalyzed synthesis of benzoxazoles, benzothiazoles and benzimidazoles using dioxygen as oxidant

期刊

RSC ADVANCES
卷 4, 期 34, 页码 17832-17839

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra00559g

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资金

  1. National Natural Science Foundation of China [21302110, 21375075, 21302109]
  2. Taishan Scholar Foundation of Shandong Province
  3. Project of Shandong Province Higher Educational Science and Technology Program [J13LD14]
  4. Natural Science Foundation of Shandong Province [ZR2013BQ017]
  5. Scientific Research Foundation of Qufu Normal University [BSQD 2012021]

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A green and efficient strategy for the synthesis of benzoxazoles, benzothiazoles and benzimidazoles has been developed by using inexpensive, readily available, dioxygen-stable and recyclable CuFe2O4 as the nanocatalyst, and o-substituted aminobenzene and various aldehydes as the starting materials. The CuFe2O4 nanoparticles are dioxygen insensitive and easily recoverable with an external magnet from the reaction medium. The catalyst can be reused ten times without significant loss of catalytic activity.

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