4.6 Article

Si@SiO2 nanowires/carbon textiles cable-type anodes for high-capacity reversible lithium-ion batteries

期刊

RSC ADVANCES
卷 4, 期 35, 页码 18391-18396

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra01363h

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资金

  1. National Natural Science Foundation [91123008, 61377033]
  2. 973 Program of China [2011CB933300]
  3. Program for New Century Excellent Talents of the University in China [NCET-11-0179]
  4. Fundamental Research Funds for the Central Universities [HUST: 2013NY013]
  5. Wuhan Science and Technology Bureau [20122497]

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To fulfil the increasing demands for high-efficiency next-generation energy storage systems, different electrode matrixes have been designed to achieve the desired batteries with high energy density and long cycle life. Herein, we fabricated novel binder-free Si@SiO2 nanowires/carbon textiles cable-type anodes for Li-ion batteries applications. The half-cells based on the above electrodes delivered high reversible capacity of 2247 mA h g(-1) at 800 mA g(-1), good rate capability, and excellent cycle stability of as long as 1000 cycles at 8 A g(-1). Full batteries including the as-synthesized Si@SiO2 anodes and commercial LiCoO2 cathodes were also fabricated, which exhibited greatly enhanced performance, thus revealing that these novel Si@SiO2 nanowires/carbon textiles cable-type electrodes can be applied in next-generation energy storage devices.

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