期刊
RSC ADVANCES
卷 4, 期 33, 页码 16920-16927出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra01200c
关键词
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资金
- National Natural Science Foundation of China [21171015, 21373195]
- 1000 plan from Chinese Government
- Fundamental Research Funds for the Central Universities [WK2060140016, WK2060140014]
- Alexander von Humboldt Foundation
- program for New Century Excellent Talents in University (NCET)
N-doped hollow porous carbon nanofibers (P-HCNFs) were prepared through pyrolyzation of hollowpolypyrrole (PPy) nanofibers fabricated using electrospun polycaprolactone (PCL) nanofibers as a sacrificial template. When used as anode material for NIBs, P-HCNFs exhibit a reversible capacity of 160 mA h g(-1) after 100 cycles at a current density of 0.05 A g(-1). An improved rate capability is also obtained at even higher charge-discharge rates. When cycled at a current density of 2 A g (1), the electrode can still showa reversible capacity of 80mA h g(-1). The N-doped sites, one-dimensional nanotube structure, and functionalized surface of P-HCNFs are capable of rapidly and reversibly accommodating sodium ions through surface adsorption and redox reactions. Therefore, P-HCNF is a promising anode material for next-generation NIBs.
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