期刊
RSC ADVANCES
卷 4, 期 70, 页码 37342-37348出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra04209c
关键词
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资金
- National Natural Science Foundation of China [21375079, 21105056]
- Project of Development of Science and Technology of Shandong Province, China [2013GZX20109]
In this paper, hair, which is composed of 99% keratin and 1% other elements, is chosen as a carbon source for nitrogen-doped carbon nanomaterials. By hydrothermal treatment of hair in water without any additives, such as salts, acids, or bases, carbon nanospheres with a photoluminescent quantum yield of 24.8% have been prepared. When the excitation wavelength changes from 300 to 480 nm, the photoluminescent peak shifts from 422 (violet) to 520 nm (green). Fourier transform infrared and X-ray photoelectron spectroscopy spectra analysis shows the carbon nanospheres are functionalized with hydroxyl, amino, carbonyl, and carboxylic acid groups. The carbon nanospheres have been further used as a novel probe for label-free detection of Hg2+ ions. The method possesses high sensitivity and selectivity. The linear range for Hg2+ ions is 10 to 100 nM. Meanwhile, the detection can be easily accomplished with a onestep rapid operation. This sensing system has been successfully used for the analysis of river water samples.
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