期刊
RSC ADVANCES
卷 4, 期 69, 页码 36419-36424出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra07246d
关键词
-
资金
- National Natural Science Foundation of China [51010002, 51272229, 51272231]
- Zhejiang Provincial Natural Science Foundation of China [LR13E020001]
- Qianjiang Talent Project [QJD1302009]
- Welch Foundation [AX-1730]
A new microporous metal-organic framework Cu-6(DDCBA)(3) (ZJU-72, H(5)DDCBA = 3,5-di(3',5'-dicarboxylpheny)-benozoic acid) with open metal sites and exposed carboxylate groups is rationally designed and synthesized, exhibiting a low binding energy of 9.7 kJ mol(-1) for C2H2 and 15.1 kJ mol(-1) for CO2 and a high separation selectivity of 39.7 for C2H2/CH4 at 298 K and 8.2 for CO2/CH4 at 273 K.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据