期刊
RSC ADVANCES
卷 4, 期 27, 页码 14013-14023出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra46722h
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资金
- Department of Science AMP
- Technology, New Delhi
- CSIR, New Delhi
- CSIR-ORIGIN [CSC 0108]
- CSIR-ACT [CSC0301]
- CSIR-OSDD [HCP-0001]
A wide range of 3-substituted isoquinolines, steroidal pyridines, 5,6-dihydrobenzo[f]isoquinolines and 1,6-naphthyridine were synthesized in good yield via a ligand-free copper-catalyzed three-component reaction of beta-halovinyl/aryl aldehyde, aromatic/aliphatic terminal alkyne and tert-butylamine/benzamidine in DMF under microwave irradiation. A catalyst-free reaction of ortho-alkynyl aryl/vinyl aldehydes with benzamidine under microwave irradiation also provided the 3-substituted isoquinoline and substituted pyridine derivatives in excellent yield.
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