期刊
RSC ADVANCES
卷 4, 期 25, 页码 12844-12848出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra46829a
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资金
- National Nature Sciences Foundation of China [21303118, 20973095, 51202159]
- Seed Foundation of Tianjin University
- Jiangsu Province Key Laboratory of Fine Petrochemical Engineering
In this work, lanthanum (La)-based coordination polymers (CPs) microplates were fabricated in a simple bottom-up way by hydrothermal reaction of La3+ and a green ligand EDTA (ethylenediamine-N,N,N',N'-tetraacetate). Under similar conditions, cerium (Ce)-EDTA CPs microplates could also be fabricated, which had the same crystalline phase and similar chemical composition to the La-EDTA CPs. The formation mechanism of the La-EDTA CPs was investigated and proved to follow the Ostwald ripening process. Moreover, its morphology could be tuned facilely by varying the quantity of EDTA and the total concentrations of reactants, and several kinds of micro/nanostructures were produced such as nanoparticle clusters, nanofibers, large or uniform microplates. Furthermore, the as-prepared La-EDTA CPs exhibited green light emission property after doping with Tb3+, and La2O3 nanorods as well as CeO2 microplates were also prepared by calcination of their corresponding CPs precursors.
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