期刊
RSC ADVANCES
卷 4, 期 80, 页码 42566-42568出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra05854b
关键词
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资金
- National Natural Science Foundation of China [21376212, 21222601]
- Ministry of Education of China [20120101120107]
- Natural Science Foundation of Zhejiang Province, China [LY13B060001]
This study reports on the first transfer hydrogenation of 2-substituted quinolines promoted by a thiourea catalyst with Hantzsch ester as the hydrogen source. A wide range of quinoline derivatives, including 2-alkylquinolines and 2-arylquinolines, were efficiently reduced to give 1,2,3,4-tetrahydroquinolines with good to excellent yields. The operational simplicities and conveniences of this reaction pathway render this protocol considerably promising in the preparation of biologically active tetrahydroquinoline derivatives.
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