In moist environments biaxially-oriented corona-treated polyethylene terephthalate (BOPET) film undergoes a decay in surface energy with time. This decay is a significant and well-known problem and it considerably restricts the industrial application of BOPET film. In the present study the decay effect and the dynamics of corona-treated BOPET film in an aqueous environment have been studied using water contact angle and variable angle X-ray photoelectron spectroscopy (XPS) measurements. In addition the surface decay mechanism of the corona-treated BOPET film in aqueous environments was analyzed and a molecular moving model for the decay mechanism is proposed.
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