期刊
RSC ADVANCES
卷 4, 期 63, 页码 33416-33423出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra04960h
关键词
-
资金
- Japan Society for the Promotion of Science (JSPS) KAKENHI [25340130]
- International Research Group 'ECSAW' (Environmental Catalysis for Sustaining Clean Air and Water)
Structure-controlled well-dispersed Au-Pd nanoparticles were successfully stabilized in a commercial ion-exchange resin. The so-obtained Au-Pd nanoparticles were tested in liquid phase glycerol partial oxidation in the presence of molecular oxygen. They exhibited better catalytic performances than homologous monometallic Au or Pd catalysts. The optimized bimetallic catalyst trapped in the matrix of the ion-exchange resin was very stable with time on stream (>4000 min) using a fixed bed flow type reactor, with a conversion of ca. 50% and stable selectivities towards glyceric and tartronic acids, of ca. 60% and 30%, respectively. The active phase originated from the presence of nanometric bimetallic nanoparticles (1.0-3.0 nm) characterized by STEM analysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据