期刊
RSC ADVANCES
卷 4, 期 89, 页码 48254-48259出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra07122k
关键词
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资金
- National Natural Science Foundation of China [20906008, 21176037, 21373037, 51273030]
- Fundamental Research Funds for the Central Universities [DUT09RC (3) 158, DUT13RC (3) 41]
Highly dispersed Au-Pd nanoparticles (NPs) with an average size of similar to 3.0 nm were synthesized by in situ reduction of HAuCl4 and PdCl2 on an amine-functionalized SiO2 support. The structural and electronic properties of the Au-Pd NPs were investigated systematically using STEM-EDX, XRD, UV-vis and XPS spectroscopy. It is demonstrated that the composition of the Au-Pd NPs can be tuned by varying the ratio of Au- to Pd-containing salt in solution. In the aqueous-phase hydrodechlorination of chlorobenzene, the Au-Pd NPs showed a much higher activity and chlorine resistance than the monometallic Au and Pd counterparts. The effects of base and solvent on the activity over the supported Au-Pd NPs were also investigated.
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