期刊
RSC ADVANCES
卷 3, 期 36, 页码 15987-15992出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra42572j
关键词
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资金
- National Natural Science Foundation of China [21275135]
- National Basic Research Program of China (973 Program) [2020CB933600]
A sensitive hydrogen peroxide (H2O2) sensor was fabricated based on a Prussian blue @ gold nanocomposite (PB@Au). Au nanoparticles (Au NPs) were first electrodeposited on a glassy carbon electrode (GCE) to increase the conductivity and to catalyze the chemical deposition of PB. Electrochemical measurements showed that the PB@Au modified electrode exhibited good electrocatalytic behavior for the detection of H2O2 with a wide linear range from 2 mu M to 8.56 mM (R-2 = 0.9980), a low detection limit down to 0.1 mu M (S/N = 3), and a high sensitivity of 39.72 mu A mM(-1). The sensor also displayed a good anti-interference ability, an acceptable reproducibility, an excellent long-term stability and good repeatability. The desirable recoveries achieved in disinfected fetal bovine serum verified that the developed sensor could have a potential use in the detection of H2O2 in real samples. Moreover, the operating simplicity and low expense of the fabrication made the as-prepared electrode attractive.
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