4.6 Article

Organic polymer material with a multi-electron process redox reaction: towards ultra-high reversible lithium storage capacity

期刊

RSC ADVANCES
卷 3, 期 10, 页码 3227-3231

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra21187h

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资金

  1. National Natural Science Foundation of China [20901046]
  2. Ministry of Science and Technology [2011CB935902, 2010DFA72760, 2013AA050903, 2011AA11A257, 2013CB934000]
  3. Tsinghua University Initiative Scientific Research Program [2010THZ08116, 2011THZ08139, 2011THZ01004, 2012THZ08129]
  4. State Key Laboratory of Automotive Safety and Energy [ZZ2012-011]

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Sulfur chain grafted poly(pyridinopyridine) (SPPY) presents an over five-electron process redox reaction, a high reversible capacity of up to 1750 mAh g(-SPPY)(-1) and excellent cycling stability. Combined with its facile and eco-efficient synthesis, SPPY is a potential green material for ultra-high capacity of reversible lithium storage and opens a new widow to seek ultra-high capacity materials for lithium ion batteries.

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