期刊
RSC ADVANCES
卷 3, 期 19, 页码 6803-6806出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra40974k
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资金
- Grants-in-Aid for Scientific Research [24550247] Funding Source: KAKEN
Commercially available anthraquinones were smoothly converted to either symmetrically or unsymmetrically substituted 9,10-bis(perfluoroalkyl)anthracene-9,10-diols by way of bistrifluoromethylation or successive trifluoromethylation-nucleophilic perfluoroalkylation, respectively, and these diols can be easily aromatized to form bis(perfluoroalkyl) anthracene derivatives in good yields by treatment with a mixture of CBr4 and PPh3. Further cross-coupling reactions using halogen-containing anthracene derivatives realized a successful extension of the original pi-conjugation systems.
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