期刊
RSC ADVANCES
卷 3, 期 6, 页码 1666-1668出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra22374k
关键词
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资金
- National Natural Science Foundation of China [21142001, 21102072, 21272113]
- Research Fund for the Doctoral Program of Higher Education of China [20110091120008]
A highly enantioselective intramolecular aza-Michael addition with enone carbamates catalyzed by chiral Bronsted acids was developed. A domino cross metathesis/aza-Michael addition for the preparation of 2-substituted pyrrolidines or benzopyrrolidines was also explored. The reactions described here provide an efficient asymmetric protocol for enantio-enriched heterocycles, especially 2-substituted pyrrolidines.
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