期刊
RSC ADVANCES
卷 2, 期 20, 页码 7747-7753出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra20667f
关键词
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资金
- Knowledge Innovation Program of the Chinese Academy of Sciences [KJCX2-YW-W26]
- Beijing Municipal Science and Technology Commission [Z111100056011007]
- National Natural Science Foundation of China [21001103, 51025726]
Graphene has been widely applied as a promising supercapacitor material based on the electric double-layer mechanism. In order to solve the dispersed problem of graphene, noncovalent functionalized graphene is prepared. However, not all of these functionalized graphene materials can be employed in supercapacitors due to non-electrochemically activated molecules absorbed on graphene. Here we find a route of chemical activation with KOH to transfer noncovalent functionalized graphene to a graphene-activated carbon composite with a high specific surface area. Stable graphene colloids absorbed by oligomers of p-phenylene diamine was produced during the reduction of graphite oxide. KOH can homogeneously contact the solid graphene nanosheets after drying the colloid. Chemical activation by annealing the graphene based hybrid with KOH leads to a greatly increased specific surface area of 798 m(2) g(-1). The resulting graphene-activated carbon composite has a good capacitance of 122 F g(-1) and energy density of 6.1 Wh kg(-1) in aqueous electrolyte. The supercapacitor exhibits maximum energy densities of 52.2 and 99.2 Wh kg(-1) in an ionic liquid electrolyte at room temperature and 80 degrees C, respectively.
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