期刊
RSC ADVANCES
卷 2, 期 13, 页码 5539-5542出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra20342a
关键词
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资金
- JNCASR
- Department of Biotechnology (DBT), India
- Innovative Young Biotechnologist Award (IYBA)
- CSIR, New Delhi
Cyclo(Gly-L-Lys) epsilon-amino derivatives (1 and 2) were synthesised and exploited as low molecular weight (LMW) gelators and ordered hierarchical structures. Cyclic dipeptide (CDP) derivative 1 forms organogels in hexane, carbon tetrachloride, toluene and chloroform at minimal gelation concentrations (MGC) 5.5 wt%, 4.4 wt%, 2.6 wt% and 3.2 wt% respectively. Organogel (toluene) and hydrogel were obtained using CDP 2 at a MGC of 3.2 wt% and 2.5 wt% respectively. Interestingly, CDP 2 exhibits excimer emission in chloroform and self-assembles into ordered microporous hierarchical structures. The insight into supramolecular self-assembly of CDPs into nanofibres and ordered hierarchical structures was achieved by microscopy analysis. Presence of a network of strong intermolecular hydrogen bonding and aromatic pi-pi interactions was validated through concentration and temperature dependent NMR studies.
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