期刊
RSC ADVANCES
卷 2, 期 25, 页码 9584-9589出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra21638h
关键词
-
资金
- French-Tunisian joint project PHC-UTIQUE [09G1203]
The ruthenium-catalyzed cross-metathesis of eugenol derivatives with electron deficient olefins is reported. It is shown that in the presence of ruthenium catalysts, eugenol and its O-protected derivatives have a high tendency to undergo carbon-carbon double bond migration before and after metathesis leading to the formation of conjugated styrene derivatives. The addition of 1,4-benzoquinone suppresses these isomerization reactions and provides an efficient access to new polyfunctional phenol derivatives upon cross-metathesis of the biosourced eugenol with acrylates, acrylonitrile and acrylamides.
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