4.6 Article

Identification of (phosphine)gold(I) hydrates and their equilibria in wet solutions

期刊

RSC ADVANCES
卷 2, 期 33, 页码 12686-12689

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra22282e

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资金

  1. National Natural Science Foundation of China [20932009, 20921091]
  2. Ministry of Science and Technology of China [2012ZX09502-002]

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The elusive gold(I) hydrates [Ph3PAu(OH2)]+TfO- and [((Ph3PAu)(2)OH)(2)](2+)(TfO-)(2) resulting from the most common gold(I) pre-catalyst Ph3PAuOTf have been characterized, leading to disclosure of the equilibria between gold oxo species in wet solutions.

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