期刊
RSC ADVANCES
卷 2, 期 22, 页码 8502-8507出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra20945d
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- JST PRESTO program
Organic ionic plastic crystals (OIPCs) with cyclic perfluoroalkyl sulfonylamide as a counter anion were synthesized with an intention of expanding the temperature range of their plastic crystalline phase. The thermal analysis of the obtained OIPCs showed a solid-solid phase transition below room temperature and a high melting point above 250 degrees C, that indicated their plastic crystalline behavior in a wide temperature range, as well as thermal durability up to approximately 370 degrees C. The electrochemical measurements of these OIPCs revealed the solid-state ionic conductivity of the plastic crystalline phase and a wide electrochemical window between 0.4 and 6.2 V vs. Li/Li+.
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