4.6 Article

Synthesis of Co3O4@SnO2@C core-shell nanorods with superior reversible lithium-ion storage

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RSC ADVANCES
卷 2, 期 25, 页码 9511-9516

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra21765a

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资金

  1. 863 Project [2011AA050517]
  2. NSFC [51002133]
  3. Innovation Team Project of Zhejiang Province [2009R50005]

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This paper describes a facile hydrothermal and subsequent carbonization approach for the synthesis of Co3O4@SnO2@C core-shell nanorods. The as-synthesized Co3O4@SnO2@ C nanorods have been applied as anode materials for lithium-ion batteries, which exhibit improved cyclic performance and enhanced power capability. Both Co3O4 and SnO2 are electrochemically active materials, and the hybridization of Co3O4 and SnO2 into an integrated core-shell nanorod structure makes them an elegant synergistic effect when participating in the lithium-ion charge-discharge process. In addition, the carbon matrix has good volume buffering effect and high electronic conductivity, which may be responsible for the improved electrochemical performance.

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