期刊
RSC ADVANCES
卷 1, 期 1, 页码 117-122出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ra00281c
关键词
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资金
- MOE (Singapore) [Tier 1 RG 31/08, NRF2009EWT-CERP001-026]
- Singapore Ministry of Education [MOE2010-T2-1-017]
- A*STAR SERC [1021700144]
- Singapore MPA [23/04.15.03]
- MOE in Singapore [MOE2010-T2-1-060]
- NTU, Singapore [FY 2010 (M58120031)]
Hydrated vanadium pentoxide (V2O5 center dot 0.44H(2)O, HVO) nanobelts were synthesized by a simply high-yield (e. g. up to similar to 99%) hydrothermal approach. The length of these nanobelts was up to several hundred micrometers while the diameter was only similar to 20 nm and the thickness was similar to 10 nm. Binder-free bulky papers were prepared by using these HVO nanobelts and were tested as Li ion battery cathodes. The unique architecture of the HVO bulky paper provides hierarchical porous channels and large specific surface area, which facilitate fast ion diffusion and effectively strain relaxation upon charge-discharge cycling. The electrochemical tests revealed that the flexible HVO cathode could deliver high reversible specific capacities with similar to 100% Coulombic efficiency, especially at high C rates. For example, it achieved a reversible capacity of 163 mAh g(-1) at 6.8 C.
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