期刊
MATERIALS
卷 7, 期 3, 页码 2062-2086出版社
MDPI
DOI: 10.3390/ma7032062
关键词
alumina; impregnation; sol-gel; trichloroethylene
类别
资金
- UANL [PAICyT 1249-06]
- PAPIIT-UNAM research grant [IN207511]
- FOINS CONACYT collaboration network Nanoscience and Nanotechnologies
- [PROMEP/103.5/09/1306]
The role of iron in two modes of integration into alumina catalysts was studied at 0.39 wt% Fe and tested in trichloroethylene combustion. One modified alumina was synthesized using the sol-gel method with Fe added in situ during hydrolysis; another modification was performed using calcined alumina, prepared using the sol-gel method and impregnated with Fe. Several characterization techniques were used to study the level of Fe modification in the gamma-Al2O3 phase formed and to correlate the catalytic properties during trichloroethylene (TCE) combustion. The introduction of Fe in situ during the sol-gel process influenced the crystallite size, and three iron species were generated, namely, magnetite, maghemite and hematite. The impregnated Fe-alumina formed hematite and maghemite, which were highly dispersed on the gamma-Al2O3 surface. The X-ray photoelectron spectra (XPS), FT-IR and Mssbauer spectroscopy analyses revealed how Fe interacted with the gamma-Al2O3 lattice in both catalysts. The impregnated Fe-catalyst showed the best catalytic performance compared to the catalyst that was Fe-doped in situ by the sol-gel method; both had better catalytic activity than pure alumina. This difference in activity was correlated with the accessibility of the reactants to the hematite iron species on the surface. The chlorine poisoning for all three catalysts was less than 1.8%.
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