期刊
MATERIALS
卷 6, 期 4, 页码 1205-1236出版社
MDPI AG
DOI: 10.3390/ma6041205
关键词
arylenevinylenes; fluorinated materials; Stille cross-coupling; organic semiconductors; conjugated materials
类别
资金
- Italian National Council of Research (CNR), -Progtto EFOR
- Ministero dell'Istruzione, dell'Universita e della Ricerca, USA (MIUR)
- Universita degli Studi di Bari Aldo Moro
In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reaction has been successfully applied as a versatile synthetic protocol to prepare a wide series of pi-conjugated compounds, selectively fluorinated on the aromatic and/or vinylene units. The impact of fluoro-functionalization on properties, the solid state organization and intermolecular interactions of the synthesized compounds are discussed, also in comparison with the non-fluorinated counterparts. Luminescent and photovoltaic applications are also discussed, highlighted the role of fluorine on the performance of devices.
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