期刊
MATERIALS
卷 6, 期 6, 页码 2285-2294出版社
MDPI
DOI: 10.3390/ma6062285
关键词
spray pyrolysis; lithium ion battery; powders; anode; oxide
Ramsdellite-type lithium titanate (Li2Ti3O7) powders were synthesized by performing ultrasonic spray pyrolysis, and their chemical and physical properties were characterized by performing Scanning Electron Microscope (SEM), powder X-ray Diffraction (XRD), and Inductively Coupled Plasma (ICP) analyses. The as-prepared Li2Ti3O7 precursor powders had spherical morphologies with hollow microstructures, but an irregularly shaped morphology was obtained after calcination above 900 degrees C. The ramsdellite Li2Ti3O7 crystal phase was obtained after the calcination at 1100 degrees C under an argon/hydrogen atmosphere. The first rechargeable capacity of the Li2Ti3O7 anode material was 168 mAh/g at 0.1 C and 82 mAh/g at 20 C, and the discharge capacity retention ratio was 99% at 1 C after the 500th cycle. The cycle performance of the Li2Ti3O7 anode was also highly stable at 50 degrees C, demonstrating the superiority of Li2Ti3O7 anode materials reported previously.
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