期刊
MATERIALS
卷 4, 期 10, 页码 1648-1692出版社
MDPI
DOI: 10.3390/ma4101648
关键词
carbide; nitride; boride; transition metal; laser heating; diamond anvil cell; synthesis; extreme conditions; high pressure; high temperature
类别
资金
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- DFG [SPP1236, Wi1232, Fr2491, Ba4020]
- DAAD
- BMBF [05KS7RF1]
- COMPRES
- Consortium for Materials Properties Research in Earth Sciences under NSF [EAR 06-49658]
- Vereinigung der Freunde und Forderer der Goethe-Universitat Frankfurt
- Goethe university Frankfurt via the Hermann Willkomm foundation
- Goethe university
Transition metal nitrides, carbides and borides have a high potential for industrial applications as they not only have a high melting point but are generally harder and less compressible than the pure metals. Here we summarize recent advances in the synthesis of binary transition metal nitrides, carbides and borides focusing on the reaction of the elements at extreme conditions generated within the laser-heated diamond anvil cell. The current knowledge of their structures and high-pressure properties like high-(p,T) stability, compressibility and hardness is described as obtained from experiments.
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