期刊
NANO ENERGY
卷 18, 期 -, 页码 97-108出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2015.10.007
关键词
Core-shelf structure; Nanofiber; Etectrospinning; Phototransistor; Organic solar cells
类别
资金
- Center for Advanced Soft Electronics under the Global Frontier Research Program of the Ministry of Science, ICT and Future Planning, Korea [20110031628]
One-dimensional conjugated polymer fibers provide unperturbed percolation pathways for efficient charge transport. Here, we report the fabrication of photoresponsive core-shell organic semiconductor fibers by using co-axial electrospinning and their application to the flexible organic photovoltaic devices. The electrospun organic semiconductor fibers are encapsulated with a sheath, polyvinylpyrrolidone (PVP), and consist of the photoactive materials poly(3-hexylthiophene) and phenyl-C61-butyric acid methyl ester (P3HT:PCBM). The electrospun P3HT:PCBM fibers consist of PCBM-rich core and P3HT-rich shell phases with P3HT chains aligned along the fiber direction. This structure exhibits strong photoresponsive behavior after thermal annealing, which was assessed by implementing the fibers in a phototransistor and a photodiode. Finally, we demonstrate a novel flexible photovoltaic module device on a plastic substrate that shows reliable and stable operation under bending conditions. These electrospun polymer:PCBM blend fibers are promising components for flexible optoelectric devices. (C) 2015 Elsevier Ltd. All rights reserved.
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