Al-doped alpha-MnO2 for high mass-loading pseudocapacitor with excellent cycling stability

The Al-doped alpha-MnO2 was prepared by hydrothermal method could promote the conductivity and improve the capacitance, which demonstrated by theoretical calculation and experiments. The Al doped alpha-MnO2 electrode with a specific capacitance of about 213 F g(-1) and 146 F cm(-3) under the high mass loading of similar to 4 mg cm(-2) had excellent cycling performance that of similar to 91% maintained after 15,000 cycles. In addition, different doping amount of Al as contrast were discussed, indicating that through modification and optimization of the chemical composition of the alpha-MnO2 based electrode material by Al doping could greatly improve the electrochemical behavior and to achieve higher specific capacitance. Also, we believed that the notable cycling Life and high mass loading of Al doped alpha-MnO2 electrode material was beneficial to the application of supercapacitors. As an energy storage device, a high energy density about 2.42 mW h cm(-3) with power density of 5.72 W cm(-3) could be achieved. (C) 2014 Elsevier Ltd. All rights reserved.