期刊
GREEN CHEMISTRY LETTERS AND REVIEWS
卷 6, 期 3, 页码 233-236出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/17518253.2012.754498
关键词
catalytic transfer hydrogenation; nonionic surfactant; aqueous media; hypophosphite; palladium
资金
- Tokai University
- Tokai University Supporters Association Research and Study Grant
Palladium-catalyzed transfer hydrogenation of some organic substrates in water containing a nonionic surfactant was examined using sodium hypophosphite as a hydrogen source. Hydrogenation of organohalides such as polychloroarenes, alkenes, alkynes, nitro compounds, aromatic aldehydes, and O-benzyl and N-benzyl derivatives efficiently proceeded to give the corresponding reduction products. The addition of a nonionic surfactant, such as Tween 20, proved to be effective in obtaining satisfactory results in most cases.
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