期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 8, 期 19, 页码 4891-4899出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cy01284a
关键词
-
资金
- Cluster of Excellence RESOLV - Deutsche Forschungsgemeinschaft [EXC 1069]
- Fonds der Chemischen Industrie (FCI)
- Max Planck Society
Cu/CoO catalysts were employed for the selective oxidation of glycerol in the aqueous phase under basic conditions. The effect of the solvent on the catalytic performance was investigated and the impact on the catalyst was thoroughly elucidated. Detailed characterization of the catalysts by HR-TEM, XRD, and XPS analysis before and after the reaction revealed that the addition of co-solvents (ethanol, n-propanol, or tert-butanol) drastically altered the catalyst properties. In particular, the amount of the catalytically active CoO(OH) phase generated during the reaction depends on the co-solvent used. Generally, the co-solvent has a beneficial effect on the catalytic activity and improves the glycerol conversion by a factor of up to 1.8, which could be linearly correlated to the E-T(30) solvent polarity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据