期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 4, 期 3, 页码 599-610出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cy00671a
关键词
-
资金
- Research Grants Council of the Hong Kong Special Administrative Region, China [CityU 100409]
The deployment of fluorinated moieties to engender electronic effects through non-covalent attractive interactions is a new concept for olefin polymerization catalysts, and was proposed to account for the unprecedented living polymerization mediated by certain catalysts bearing fluorine-containing ancillary ligands. This strategy is distinct from conventional approaches based on steric influences to control olefin polymerization processes. In this perspective, the concept, generality and beneficial effects of applying non-covalent interactions to control polymerization reactions are discussed, with particular emphasis given to intramolecular C-H...F-C interactions between a fluorinated ligand and growing polymer chain.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据