4.6 Article

Efficient H-2 generation from formic acid using azole complexes in water

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CATALYSIS SCIENCE & TECHNOLOGY
卷 4, 期 1, 页码 34-37

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cy00830d

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  1. JST, ACT-C
  2. U.S. Department of Energy [DE-AC02-98CH10886]
  3. Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences

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Iridium azole-containing complexes are demonstrated to catalyze the dehydrogenation of formic acid into H-2-CO2 (1/1) mixtures in aqueous solution in the absence of organic additives, and with a maximum turnover frequency (TOF) of 34000 h(-1) at 80 degrees C.

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