期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 3, 期 11, 页码 3007-3012出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cy00250k
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资金
- MICINN [CTQ2010-16088/BQU]
- AGAUR [2009 SGR 47]
- European Research Council [321066]
- ICIQ Foundation
Chiral gold(I) phosphite complexes are readily prepared modularly from 3,3'-bis(triphenylsilyl)-1,1'-bi-2-naphthol. These chiral gold(I) phosphite complexes are very reactive precatalysts for the [4+ 2] cycloaddition of aryl-substituted 1,6-enynes with enantiomeric ratios ranging from 86 : 14 up to 94 : 6.
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