期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 2, 期 12, 页码 2436-2439出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cy20399e
关键词
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资金
- Ministerio de Ciencia e Innovacion [CTQ2009-14527]
- Comunidad de Madrid [S2009/ENE-1475]
- CSIC JAE program
- Ministerio de Ciencia e Innovacion FPI program
An inverse CeO2/CuO catalyst has been examined by XPS and DRIFTS spectroscopies under reactant mixtures relevant to the low temperature WGS process. It is shown that the presence of H2O in the reactant mixture promotes catalyst reduction by facilitating the decomposition of interfacial carbonate species which hinder the redox processes leading to generation of the species catalytically active in WGS.
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