期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 27, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201801102
关键词
anode materials; electrospray synthesis; NASICON-type structure; potassium-ion batteries; sodium-ion batteries
类别
资金
- 973 project [2015CB251103]
- Science and Technology Development Project, Jilin Province [20180101211JC, 20180101199JC, 20180101204JC]
- State Major Scientific Instrument and Equipment Development of China [2012YQ24026407]
- Jilin Province [SXGJQY2017-10, SXGJSF2017-3]
- Jilin University [SXGJQY2017-10, SXGJSF2017-3]
Identifying suitable electrode materials for sodium-ion and potassium-ion storage holds the key to the development of earth-abundant energy-storage technologies. This study reports an anode material based on self-assembled hierarchical spheroid-like KTi2(PO4)(3)@C nanocomposites synthesized via an electrospray method. Such an architecture synergistically combines the advantages of the conductive carbon network and allows sufficient space for the infiltration of the electrolyte from the porous structure, leading to an impressive electrochemical performance, as reflected by the high reversible capacity (283.7 mA h g(-1) for Na-ion batteries; 292.7 mA h g(-1) for K-ion batteries) and superior rate capability (136.1 mA h g(-1) at 10 A g(-1) for Na-ion batteries; 133.1 mA h g(-1) at 1 A g(-1) for K-ion batteries) of the resulting material. Moreover, the different ion diffusion behaviors in the two systems are revealed to account for the difference in rate performance. These findings suggest that KTi2(PO4)(3)@C is a promising candidate as an anode material for sodium-ion and potassium-ion batteries. In particular, the present synthetic approach could be extended to other functional electrode materials for energy-storage materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据