期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 29, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201801564
关键词
electrocatalysis; electronic structure; MIL-88B; MOFs; oxygen evolution reaction
类别
资金
- Thousand Talents Plan Foundation of China
- Thousand Talents Plan Foundation of Guangdong Province
- 100 Talents Plan Foundation of Sun Yat-sen University [31000-18821107]
- Program for Guangdong Introducing Innovative and Enterpreneurial Teams [2017ZT07C069]
- NSFC [21573291, 21720102007]
- STP Project of Guangzhou [201504010031]
- NSF of Guangdong Province [S2013030013474]
Exploring effective electrocatalysts for oxygen evolution reaction (OER) is a crucial requirement of many energy storage and conversion systems, involving fuel cells, water splitting, and metal-air batteries. Herein, a heterogeneity metal-organic framework (MOF) is prepared by the assembling of metals, terephthalic (A) and 2-aminoterephthalic ligands (B), defined as A(2.7)B-MOF-FeCo1.6. More importantly, A(2.7)B-MOF-FeCo1.6 exhibits excellent OER activity with an ultralow overpotential of 288 mV at 10 mA cm(-2) and a Tafel slope of 39 mV dec(-1). The high electrocatalytic performance for OER is attributed to the optimized electronic structure of the intrinsic catalytic center in MOFs via the engineering of the metal node and linkers. The work offers not only a benchmark for pure MOFs in electrocatalysis but also a new efficient strategy to improve electrocatalytic performance by electronic structure engineering of catalytic active centers in MOFs.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据