期刊
ADVANCED ENERGY MATERIALS
卷 5, 期 1, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201400867
关键词
-
类别
资金
- Joint Center for Energy Storage Research, an Energy Innovation Hub - U.S. Department of Energy, Office of Science, Basic Energy Sciences
- Natural Resources Canada
- PSI, Switzerland
- Waterloo Institute of Technology
A new lithium-ether-derived chelate ionic liquid is synthesized to serve as an electrolyte for the Li-O-2 battery that is stable to metallic lithium, and whose ethereal framework is much more inherently stable to superoxide-initiated hydrogen abstraction than the simple glyme, dimethoxyethane (DME). Reactions of chemically generated superoxide with this electrolyte show that virtually no decomposition products such as lithium formate are generated. When the electrolyte is employed in a Li-O-2 battery, a ten-fold decrease in CO2 evolution is evident on charge by comparison to DME and greatly enhanced cycling stability is observed with TiC as a cathode support. A mechanism is proposed to account for the lowered reactivity, offering new insight into the stability of organic electrolytes in Li-O-2 batteries. This approach for electrolyte design is presented here for the first time, and it can be extended to other organic systems to provide a platform for the design of advanced electrolyte systems.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据