期刊
ADVANCED ENERGY MATERIALS
卷 2, 期 11, 页码 1390-1396出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201200322
关键词
redox-active organic molecules; energy storage; redox flow batteries; quinoxaline; lithium-ions
类别
资金
- US Department of Energy, Office of Science [DE-AC02-06CH11357]
- Argonne National Laboratory
A non-aqueous lithium-ion redox flow battery employing organic molecules is proposed and investigated. 2,5-Di-tert-butyl-1,4-bis(2-methoxyethoxy)benzene and a variety of molecules derived from quinoxaline are employed as initial high-potential and low-potential active materials, respectively. Electrochemical measurements highlight that the choice of electrolyte and of substituent groups can have a significant impact on redox species performance. The charge-discharge characteristics are investigated in a modified coin-cell configuration. After an initial break-in period, coulombic and energy efficiencies for this unoptimized system are similar to 70% and similar to 37%, respectively, with major charge and discharge plateaus between 1.8-2.4 V and 1.7-1.3 V, respectively, for 30 cycles. Performance enhancements are expected with improvements in cell design and materials processing.
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