期刊
ADVANCED ENERGY MATERIALS
卷 1, 期 1, 页码 115-123出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201000009
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资金
- NSF of China [20873086, 21073122]
- Shanghai Sci. & Tech. and Edu. Committee [08JC1417100, 0852nm0090, 10XD1403300, S30406]
- Fok Ying Tung Education Fund [121013]
- program for New Century Excellent Talents in Universities [NCET-07-0560]
Graphitic carbons with ordered mesostructure and high surface areas (of great interest in applications such as energy storage) have been synthesized by a direct triblock-copolymer-templating method. Pluronic F127 is used as a structure-directing agent, with a low-molecular-weight phenolic resol as a carbon source, ferric oxide as a catalyst, and silica as an additive. Inorganic oxides can be completely eliminated from the carbon. Small-angle XRD and N-2 sorption analysis show that the resultant carbon materials possess an ordered 2D hexagonal mesostructure, uniform bimodal mesopores (about 1.5 and 6 nm), high surface area (similar to 1300 m(2)/g), and large pore volumes (similar to 1.50 cm(3)/g) after low-temperature pyrolysis (900 degrees C). All surface areas come from mesopores. Wide-angle XRD patterns demonstrate that the presence of the ferric oxide catalyst and the silica additive lead to a marked enhancement of graphitic ordering in the framework. Raman spectra provide evidence of the increased content of graphitic sp(2) carbon structures. Transmission electron microscopy images confirm that numerous domains in the ordered mesostructures are composed of characteristic graphitic carbon nanostructures. The evolution of the graphitic structure is dependent on the temperature and the concentrations of the silica additive, and ferric oxide catalyst. Electrochemical measurements performed on this graphitic mesoporous carbon when used as an electrode material for an electrochemical double layer capacitor shows rectangular-shaped cyclic voltammetry curves over a wide range of scan rates, even up to 200 mV/s, with a large capacitance of 155 F/g in KOH electrolyte. This method can be widely applied to the synthesis of graphitized carbon nanostructures.
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