期刊
ACTA METALLURGICA SINICA-ENGLISH LETTERS
卷 26, 期 6, 页码 735-741出版社
CHINESE ACAD SCIENCES, INST METAL RESEARCH
DOI: 10.1007/s40195-013-0162-4
关键词
Ni-Co alloys; Coatings; Electrodeposition; Ultrasound; Hardness; Corrosion
资金
- National Nature Science Fund of China [51204115]
In this paper, Ni-Co coatings were electrodeposited onto carbon steel substrates with the aid of ultrasonic agitation. The coatings were analyzed by energy dispersive X-ray analysis (EDX), X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). The effects of the ultrasonic frequency on the roughness, hardness and corrosion resistance of the Ni-Co coatings were also investigated. The results indicated that the increase of the ultrasonic frequency from 20 to 120 kHz reduced the Ni content and the grain size of Ni-Co coatings. Moreover, the phase structure of the electrodeposited coatings was influenced by the ultrasonic frequency. Under 55 kHz ultrasonic agitation, the Ni-Co coating was single fcc phase and showed the finest roughness and the strongest corrosion resistance in 5 wt.% NaCl solution at the ambient temperature. Under ultrasonic agitation with frequency of 90 kHz, the coating was a mixture of fcc and hcp structure and showed the maximal hardness of about 420 HV. Therefore, ultrasonic agitation helped decrease the roughness, and enhance hardness and corrosion resistance of Ni-Co coatings.
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