期刊
ACS COMBINATORIAL SCIENCE
卷 16, 期 5, 页码 211-214出版社
AMER CHEMICAL SOC
DOI: 10.1021/co5000322
关键词
cross-coupling reactions; solid-phase organic synthesis; Hiyama coupling
资金
- CONICET
- ANPCyT
- Fundacion Prats
- Universidad Nacional de Rosario from Argentina
The solid-phase version of the Pd-catalyzed Hiyama reaction between a variety of aryltriethoxysilanes and immobilized aryl halides was developed. Smooth cross coupling was achieved to afford the corresponding biaryl products in moderate to excellent yields. The described protocol would be particularly useful for the construction of 4 '-substituted 1,1 '-biphenyl derivatives.
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